8-Methyl-5-methylene-2-oxotricyclo[5.3.1.13,9]dodecan-endo-8-ol

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8-Methyl-5-methyl­ene-2-oxotricyclo[5.3.1.13,9]dodecan-endo-8-ol

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Two mol-ecules of the title compound, C(14)H(10)N(2)OS, are hydrogen bonded about a center of inversion. In the mol-ecule, the two aromatic rings are twisted by 37.27 (5)° with respect to one another. The azomethine bond is in the E configuration.

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Crystal structure of methyl endo-8-cyano-exo-8-methyl-3-oxo-2-oxabicyclo[2.2.2]oct-5-ene-6-carboxylate.

A photochemical cycloaddition reaction of methyl 2-pyrone-5-carboxylate with methacrylonitrile mainly gave a [4 + 2] cycloadduct, assigned as methyl endo-8-cyano-exo-8-methyl-3-oxo-2-oxabicyclo[2.2.2]oct-5-ene-6-carboxylate, whose structure was determined by an X-ray diffraction study. The formation of the cycloadduct was reasonably explained by considering a biradical intermediate having a les...

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5,7-Dibromo-2-methyl­quinolin-8-ol

In the title compound, C(10)H(7)Br(2)NO, the mol-ecule possesses a planar geometry with an r.m.s deviation of 0.0383 Å for all non-H atoms. The crystal structure displays O-H⋯N and C-H⋯O hydrogen bonding, as well as Br⋯Br contacts [3.6284 (4) Å].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808009677